Synthesis and Characterisation of Azo-Based Dichlorotriazine Reactive Dye with Halochromic Behaviour

Mustafijur Rahman; Mohammad Abbas Uddin; Md. Moynul Hassan Shibly; Nusrat Binta Hossain; Mohammad Forhad Hossain; Muriel Rigout

doi:10.14502/Tekstilec2021.64.247-259

Authors

Mustafijur Rahman Department of Dyes and Chemicals Engineering, Bangladesh University of Textiles, Dhaka, Bangladesh Author https://orcid.org/0000-0001-8411-0933
Mohammad Abbas Uddin Department of Dyes and Chemicals Engineering, Bangladesh University of Textiles, Dhaka, Bangladesh Author
Md. Moynul Hassan Shibly Department of Textile Engineering, Primeasia University, Dhaka, Bangladesh Author
Nusrat Binta Hossain Puls Trading Far East Limited, H&M Bangladesh Liaison Office, Dhaka, Bangladesh Author
Mohammad Forhad Hossain Department of Dyes and Chemicals Engineering, Bangladesh University of Textiles, Dhaka, Bangladesh Author
Muriel Rigout School of Design, University of Leeds, Leeds, LS2 9JT, UK Author

DOI:

https://doi.org/10.14502/Tekstilec2021.64.247-259

Keywords:

chromism, H-acid, 4-nitroaniline, synthesis, halochromic, dichlorotriazine, reactive dye

Abstract

Halochromism or pH sensitivity has tremendous potential for applications in various textile fields, such as protective clothing, wound dressings, etc. Reactive dye is mostly used to colour cotton or other regenerated cellulose fibres due to its better fastness and wide range of hue, from vivid to dull shades. In this research work, an azo-based dichlorotriazine reactive dye was synthesised from H-acid (4-amino-5-hydroxy-2,7-naphthalenedisulfonic acid) and 4-nitroaniline, which incorporates a halochromic behaviour. The change of colour of this dye was evaluated both in the the solution stage and coloured fabric stage in various pH solutions. A visible change of colour with the alteration of pH was observed after dyeing textile fabric with the synthesised dye. However, a significant difference was observed in a few cases with regard to the change of colour with the alteration of pH in the solution stage and coloured fabric stage. The dyed fabric also displayed very good to excellent wash fastness properties. Generally, the reactive dye synthesised in this research demonstrated an obvious change of colour with the alteration of the pH level.

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