Fastness Improvement of a Crystalline Liquid Thermochromic Print on Cotton Fabric by the Application of Silica Nanoparticles from Rice-Husk

Authors

  • Jantera Sekar Tirta Politeknik STTT Bandung, Bandung, Indonesia
  • Hoerudin Indonesian Center for Agricultural Postharvest Research and Development, Bogor, Indonesia
  • Ida Nuramdhani Politeknik STTT Bandung, Bandung, Indonesia; Department of Textile Chemistry, Politeknik STTT Bandung, Bandung, Indonesia https://orcid.org/0000-0002-1034-3598

DOI:

https://doi.org/10.14502/tekstilec.65.2022061

Keywords:

rice husk, silica, thermochromic dyes, liquid crystal, printing

Abstract

Most commercially available thermochromic dyes are not resistant to washing and rubbing when applied to textile materials. This is due to their low affinity for fibre. The addition of silica extracted from rice husk ash using the sol-gel method was performed to improve colour fastness and maintain the stability of thermochromic dyes printed on cotton fabrics. The rice husks used in this study were derived from the Baroma rice variety with silica content in ash and silica gel of 97.05% and 99.20%. The morphological structures and particle sizes of the silica obtained were analysed using a scanning electron microscope (SEM) and particle size analyser (PSA). The particle sizes of the silica product, thermochromic dye and silica-dye mixture were 53.64–60.66 nm, 2.603 nm and 5.827 nm, respectively. The printing process of silica: the dye mixture was applied to cotton fabric in a ratio of 1:1. Fluid of silica: the dye showed good stability until the seventh day of observation. Colour fastness to washing assessed using a staining scale was better with the addition of silica than without silica, i.e. 3–4 in the first washing and 3 in the third washing. Similarly, fastness to rubbing was also better with the addition of silica, i.e. 3–4 dry rubbings and 3 wet rubbings. Moreover, the combination of silica, binder, PDMS and dye (in a ratio of 1:1:1:1) gave the best colour fastness to washing and rubbing.

References

FERRARA, M., BENGISU, M. Intelligent design with chromogenic materials. JAIC-Journal of the International Colour Association, 2014, 13, 54–66, https://aic-color.org/resources/Documents/jaic_v13_06_GdC2013.pdf.

CHOWDHURY, M.A., BUTOLA, B.S., JOSHI, M. Application of thermochromic colorants on textiles: temperature dependence of colorimetric properties. Coloration Technology, 2013, 129(3), 232–237, doi: 10.1111/cote.12015. DOI: https://doi.org/10.1111/cote.12015

JAKOVLJEVIĆ, M., KULČAR, R., PASANEC PREPROTIĆ, S., POLJIČAK, A., KLANJŠEK GUNDE, M. Dynamic colour changes of thermochromic leuco dye and liquid crystal based printing inks. In International Joint Conference on Environmental and Light Industry Technologies, 20 – 22 November 2013, Budapest, Hungary, doi: 10.13140/RG.2.2.34274.56005.

BAMFIELD, P., HUTCHINGS, M.G. Chromic phenomena: technological applications of colour chemistry. Cambridge : Royal Society of Chemistry, 2010, 9–20, doi: 10.1039/9781849731034-FP009. DOI: https://doi.org/10.1039/9781849731034-FP009

LCR Hallcrest. Handbook of thermochromic liquid crystal technology. Glenview : Hallcrest, 2014.

AITKEN, D., BURKINSHAW, S.M., GRIFFITHS, J., TOWNS, A.D. Textile applications of thermochromic systems. Review of Progress in Coloration and Related Topics, 1996, 26(1), 1–8. DOI: https://doi.org/10.1111/j.1478-4408.1996.tb00105.x

GOBALAKRISHNAN, M., THANABAL, V., RAJESH KUMAR, S., ASHOK KUMAR, A. The effect of binders on the fastness properties of thermochromic dyes. International Journal of Engineering Trends and Technology, 2020, 68(2), 61–63. DOI: https://doi.org/10.14445/22315381/IJETT-V68I2P211

SOBKOVÁ, M. The application aspects of thermochromic textile coating : Master’s Thesis. [Brno : University of Technology, Faculty of Chemistry], 2018, https://www.vut.cz/www_base/zav_prace_soubor_verejne.php?file_id=170153.

RIBEIRO, L.S., PINTO, T., MONTEIRO, A., SOARES, O.S.G.P., PEREIRA, C., FREIRE, C., PEREIRA, M.F.R. Silica nanoparticles functionalized with a thermochromic dye for textile applications. Journal of Materials Science, 2013, 48(14), 5085–5092, doi: 10.1007/s10853-013-7296-7. DOI: https://doi.org/10.1007/s10853-013-7296-7

MAHLTIG, B., HAUFE, H., BÖTTCHER, H. Functionalisation of textiles by inorganic sol-gel coatings. Journal of Materials Chemistry, 2005, 15(41), 4385–4398, doi: 10.1039/b505177k. DOI: https://doi.org/10.1039/b505177k

Luas panen dan produksi padi di Indonesia 2021 [online]. Badan Pusat Statistik [accessed 10 November 2022]. Available on World Wide Web: <https://www.bps.go.id/publication/2022/07/12/c52d5cebe530c363d0ea4198/luas-panen-dan-produksi-padi-di-indonesia-2021.html#:~:text=Abstraksi,54%2C42%20juta%20ton%20GKG>.

SINGH, B. Rice husk ash. In Waste and Supplementary Cementitious Materials in Concrete: Characterisation, Properties, and Applications. Edited by Rafat Siddique and Paulo Cachim. Elsevier, 2018, 417–460, doi: 10.1016/B978-0-08-102156-9.00013-4. DOI: https://doi.org/10.1016/B978-0-08-102156-9.00013-4

BAKAR, R.A., YAHYA, R., GAN, S.N. Production of high purity amorphous silica from rice husk. Procedia Chemistry, 2016, 19, 189–195, doi: 10.1016/j.proche.2016.03.092. DOI: https://doi.org/10.1016/j.proche.2016.03.092

RAHMAN, I.A., PADAVETTAN, V. Synthesis of silica nanoparticles by sol-gel: size-dependent properties, surface modification, and applications in silica-polymer nanocompositesa review. Journal of Nanomaterials, 2012, 2012, doi: 10.1155/2012/132424. DOI: https://doi.org/10.1155/2012/132424

DESSIE, A., ESHETU, B. The role of binders and its chemistry in textile pigment printing. Journal of Textile Science & Engineering, 2021, 11(1), 1–6.

LIOU, T.H., YANG, C.C. Synthesis and surface characteristics of nanosilica produced from alkali-extracted rice husk ash. Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 2011, 176(7), 521–529, doi: 10.1016/j.mseb.2011.01.007. DOI: https://doi.org/10.1016/j.mseb.2011.01.007

SETYAWAN, N., HOERUDIN, WULANAWATI, A. Simple extraction of silica nanoparticles from rice husk using technical grade solvent: effect of volume and concentration. IOP Conference Series: Earth and Environmental Science, 2019, 309(1), 1–8, doi: 10.1088/1755-1315/309/1/012032. DOI: https://doi.org/10.1088/1755-1315/309/1/012032

KUŚMIEREK, K., ŚWIĄTKOWSKI, A. The influence of different agitation techniques on the adsorption kinetics of 4-chlorophenol on granular activated carbon. Reaction Kinetics, Mechanisms and Catalysis, 2015, 116(1), 261–271, doi: 10.1007/s11144-015-0889-1. DOI: https://doi.org/10.1007/s11144-015-0889-1

CHINDAPRASIRT, P., RATTANASAK, U. Eco-production of silica from sugarcane bagasse ash for use as a photochromic pigment filler. Scientific Reports, 2020, 10(1), 1–8, doi: 10.1038/s41598-020-66885-y. DOI: https://doi.org/10.1038/s41598-020-66885-y

Temperature responsive liquid crystal sprayable ink [online]. SFXC [accessed 10 November 2022]. Available on World Wide Web: <https://www.sfxc.co.uk/products/sfxc-sprayable-liquid-crystal-ink>.

Instructions for liquid crystal ink [online]. Good Life Innovations Ltd (Special FX Creative) [accessed 10 November 2022]. Available on World Wide Web: <https://findmydata.cloud/uploads/pdf/liquid-crystal-ink-24c-to-29c-7.pdf>.

HARIYATNO, S.P., PARAMITA, V., AMALIA, R. The effect of surfactant, time, and speed of stirring in the emulsification process of soybeaan oil in water. Journal of Vocational Studies on Applied Research, 2021, 3(1), 21–25. DOI: https://doi.org/10.14710/jvsar.v3i1.10918

Homemade Peltier cooler / fridge with temperature controller DIY [online]. DIY Electronics [accessed 10 November 2022]. Available on World Wide Web: <https://www.instructables.com/Homemade-Peltier-Cooler-W-Temperature-Control-DIY-/>.

PILKINGTON, P.H., MARGARITIS, A., MENSOUR, N.A., RUSSELL, I. Fundamentals of immobilised yeast cells for continuous beer fermentation: a review. Journal of the Institute of Brewing, 1998, 104(1), 19–31, doi: 10.1002/j.2050-0416.1998.tb00970.x. DOI: https://doi.org/10.1002/j.2050-0416.1998.tb00970.x

NEDOVIC, V.A., OBRADOVIC, B., LESKOSEK-CUKALOVIC, I., VUNJAK-NOVAKOVIC, G. Immobilized yeast bioreactor systems for brewing – recent achievements. In Engineering and Manufacturing for Biotechnology. Edited by Marcel Hofman and Philippe Thonart. (Focus on Biotechnology, vol 4). Dordrecht : Springer, 2001, 277–292, doi: 10.1007/0-306-46889-1_18. DOI: https://doi.org/10.1007/0-306-46889-1_18

CHRISTIE, R.M. Chromic materials for technical textile applications. In Advances in the Dyeing and Finishing of Technical Textiles. Edited by M.L. Gulrajani. Elsevier, 2013, 3–36, doi: 10.1533/9780857097613.1.3. DOI: https://doi.org/10.1533/9780857097613.1.3

ASADUZZAMAN, M., HOSSAIN, F., KAMRUZZAMAN, M., MIAH, M.R. Effects of binder and thickeners of pigment printing paste on fastness properties of printed fabric. International Journal of Scientific and Engineering Research, 2016, 7(9), 710–719.

Wacker Chemie AG [online]. WACKER [accessed 10 November 2022]. Available on World Wide Web: < https://www.wacker.com>.

AYAZI-YAZDI, S., KARIMI, L., MIRJALILI, M., KARIMNEJAD, M. Fabrication of photochromic, hydrophobic, antibacterial, and ultraviolet-blocking cotton fabric using silica nanoparticles functionalized with a photochromic dye. The Journal of the Textile Institute, 2017, 108(5), 856–863, doi: 10.1080/00405000.2016.1195088. DOI: https://doi.org/10.1080/00405000.2016.1195088

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Published

2022-11-29

How to Cite

Tirta, J. S., Hoerudin, & Nuramdhani, I. (2022). Fastness Improvement of a Crystalline Liquid Thermochromic Print on Cotton Fabric by the Application of Silica Nanoparticles from Rice-Husk. Tekstilec, 65(4), 246–255. https://doi.org/10.14502/tekstilec.65.2022061

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Scientific article