Investigation of Bleaching of Cotton Fabrics with UV-TiO2

Authors

  • Semiha Eren Uludağ University, Faculty of Engineering, Textile Engineering Department, Görükle Campus, Nilüfer, Bursa, Turkey Author https://orcid.org/0000-0002-2326-686X
  • Aliye Akarsu Özenç Uludağ University, Faculty of Engineering, Textile Engineering Department, Görükle Campus, Nilüfer, Bursa, Turkey Author

DOI:

https://doi.org/10.14502/tekstilec.66.2023019

Keywords:

ultraviolet, Photocatalytic, TiO2, cotton

Abstract

Titanium dioxide exhibits photocatalytic properties under ultraviolet (UV) irradiation. In this study, an environmentally friendly, fast and efficient technique for bleaching cotton fabrics is presented, utilising the photocatalytic property of TiO2. Raw cotton fabric samples were treated with TiO2-containing and TiO2-free treatment solutions (hydrogen peroxide and sodium hydroxide) under UV irradiation in order to bleach the samples. The results showed that cotton fabrics treated with TiO2 were bleached satisfactorily without severe strength loss.

Downloads

Download data is not yet available.

References

VARESANO, A., ALUIGI, A., FLORIO, L., FABRIS, R. Multifunctional cotton fabrics. Synthetic Metals, 2009, 159(11), 1082−1089, doi: 10.1016/j.synthmet.2009.01.036.

BULUT, Y., ERDOĞAN, Ü.H. Selüloz Esasli Doğal Liflerin Kompozit Üretiminde Takviye Materyali Olarak Kullanimi. Tekstil ve Mühendis, 2011, 18(82), 26−35.

REN, X., BUSCHLE-DILLER, G. Oxidoreductases for modification of linen fibers. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2007, 299(1−3), 15−21, doi: 10.1016/j.colsurfa.2006.11.011.

WANG, N., TANG, P., ZHAO, C., ZHANG, Z., SUN, G. An environmentally friendly bleaching process for cotton fabrics: mechanism and application of UV/H2O2 system. Cellulose, 2020, 27(2), 1071−1083, doi: 10.1007/s10570-019-02812-3.

ZERONİAN, S.H., INGLESBY, M.K. Bleaching of cellulose by hydrogen peroxide. Cellulose, 1995, 2(4), 265−272, doi: 10.1007/BF00811817.

TANG, P., Jİ, B., SUN, G. Whiteness improvement of citric acid crosslinked cotton fabrics: H2O2 bleaching under alkaline condition. Carbohydrate Polymers, 2016, 147, 139−145, doi: 10.1016/j.carbpol.2016.04.007.

BABU, B.R., PARANDE, A.K., RAGHU, S., KUMAR, T.P. Cotton textile processing: waste generation and effluent treatment. Journal of Cotton Science, 2007, 11, 141−153.

BARROS, M.A., CONCEİÇÃO, D.S., SİLVA, C.G., SAMPAİO, M.J., FARİA, J.L. Sustainable bleaching process of raw cotton by TiO2 light-activated nanoparticles. U.Porto Journal of Engineering, 2020, 6(2), 11−21, doi: 10.24840/2183-6493_006.002_0002.

WIENER, J., CHLÁDOVÁ, A., SHAHIDI, S., PETEROVÁ, L. Effect of UV irradiation on mechanical and morphological properties of natural and synthetic fabric before and after nano-TiO2 padding. Autex Research Journal, 2017, 17(4), 370−378, doi: 10.1515/aut-2017-0002.

EREN, S. Photocatalytic hydrogen peroxide bleaching of cotton. Cellulose, 2018, 25(6), 3679−3689, doi: 10.1007/s10570-018-1814-3.

GEDIK, G. Bleaching of cotton/lyocell fabrics with heterogeneous photocatalysis with titanium(IV) oxide under UV light and investigation of the effect of oxygen radicals on bleaching process. Journal of Textiles and Engineer, 2020, 27(118), 64−74, doi: 10.7216/1300759920202711802.

KILIÇ, M.Y., KESTIOĞLU, K. Endüstriyel Atıksuların Arıtımında İleri Oksidasyon Proseslerinin Uygulanabilirliğinin Araştırılması. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, 2008, 13(1), 6780.

ADAMU, H. Photocatalytic remediation of nitrate in aqueous environment by TiO2-based photocatalysts  influence of organic hole scavenger on the selectivity of reaction. In Online International Conference on Catalysis and Chemical Engineering, March 04-05, 2021.

MILLS, A., LE HUNTE, S. An overview of semiconductor photocatalysis. Journal of Photochemistry and Photobiology A: Chemistry, 1997, 108(1), 1−35, doi: 10.1016/S1010-6030(97)00118-4.

CORNISH, B.J., LAWTON, L.A., ROBERTSON, P.K. Hydrogen peroxide enhanced photocatalytic oxidation of microcystin-LR using titanium dioxide. Applied Catalysis B: Environmental, 2000, 25(1), 59−67, doi: 10.1016/S0926-3373(99)00121-6.

MONTAZER, M., MORSHEDI, S. Nano photo scouring and nano photo bleaching of raw cellulosic fabric using nano TiO2. International Journal of Biological Macromolecules, 2012, 50(4), 1018−1025, doi: 10.1016/j.ijbiomac.2012.02.018.

LI, M., DENG, T., LIU, S., ZHANG, F., ZHANG, G. Superhydrophilic surface modification of fabric via coating with nano-TiO2 by UV and alkaline treatment. Applied Surface Science, 2014, 297, 147−152, doi: 10.1016/j.apsusc.2014.01.105.

BANERJEE, S., GOPAL, J., MURALEEDHARAN, P., TYAGI, A.K., RAJ, B. Physics and chemistry of photocatalytic titanium dioxide: visualization of bactericidal activity using atomic force microscopy. Current Science, 2006, 90(10), 1378−1383.

YU, K.P., LEE, G.W. Decomposition of gas-phase toluene by the combination of ozone and photocatalytic oxidation process (TiO2/UV, TiO2/UV/O3, and UV/O3). Applied Catalysis B: Environmental, 2007, 75(1−2), 29−38, doi: 10.1016/j.apcatb.2007.03.006.

MONTAZER, M., MORSHEDI, S. Photo bleaching of wool using nano TiO2 under daylight irradiation. Journal of Industrial and Engineering Chemistry, 2014, 20(1), 83–90, doi: 10.1016/j.jiec.2013.04.023.

MURUGANANDHAM, M., SWAMINATHAN, M. Photochemical oxidation of reactive azo dye with UV–H2O2 process. Dyes and Pigments, 2004, 62(3), 269−275, doi: 10.1016/j.dyepig.2003.12.006.

FERRERO, F., MIGLIAVACCA, G., PERIOLATTO, M. UV treatments on cotton fibers. In Cotton Research. Edited by Ibrokhim Y. Abdurakhmonov. London : IntechOpen, 2016, 235−256, doi: 10.5772/63796.

UGUR, Ş.S., SARIIŞIK, M., AKTAŞ, A.H. The fabrication of nanocomposite thin films with TiO2 nanoparticles by the layer-by-layer deposition method for multifunctional cotton fabrics. Nanotechnology, 2010, 21(32), 18, doi: 10.1088/0957-4484/21/32/325603.

SINGH, S., SHARMA, V., SACHDEV, K. Investigation of effect of doping concentration in Nb-doped TiO2 thin films for TCO applications. Journal of Materials Science, 2017, 52(19), 11580−11591, doi: 10.1007/s10853-017-1328-7.

CHUNG, C., LEE, M., CHOE, E.K. Characterization of cotton fabric scouring by FT-IR ATR spectroscopy. Carbohydrate Polymers, 2004, 58(4), 417−420, doi: 10.1016/j.carbpol.2004.08.005.

ATR-FT-IR spectrum of cotton (4000–225 cm–1) [online]. Database of ATR-FT-IR spectra of various materials [accessed 4.1.2023]. Available on World Wide Web: <https://spectra.chem.ut.ee/textile-fibres/cotton/>.

EL-SHERBINY, S., MORSY, F., SAMIR, M., FOUAD, O.A. Synthesis, characterization and application of TiO2 nanopowders as special paper coating pigment. Applied Nanoscience, 2014, 4(3), 305−313, doi: 10.1007/s13204-013-0196-y.

JOHNSON, M. S., ATES, M., ARSLAN, Z., FARAH, I. O., BOGATU, C. Assessment of crystal morphology on uptake, particle dissolution, and toxicity of nanoscale titanium dioxide on Artemia salina. Journal of Nanotoxicology and Nanomedicine (JNN), 2017, 2(1), 11−27, doi: 10.4018/JNN.2017010102.

Downloads

Published

2023-06-28

Issue

Section

Scientific article

Categories

How to Cite

Eren, S., & Akarsu Özenç, A. (2023). Investigation of Bleaching of Cotton Fabrics with UV-TiO2. Tekstilec, 66, 126-133. https://doi.org/10.14502/tekstilec.66.2023019

Most read articles by the same author(s)